From the BBC
The Pope’s chief astronomer says that life on Mars cannot be ruled out. Writing in the Vatican newspaper, the astronomer, Father Gabriel Funes, said intelligent beings created by God could exist in outer space. … The search for forms of extraterrestrial life, he says, does not contradict belief in God. The official Vatican newspaper headlines his article ‘Aliens Are My Brother’.
Just as there are multiple forms of life on earth, so there could exist intelligent beings in outer space created by God. And some aliens could even be free from original sin, he speculates.
So it is possible for mere mortals to have freewill without sin!